Single-crystal X-ray structure analysis of the superionic conductor Li10GeP2S12

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Single-crystal X-ray structure analysis of the superionic conductor Li10GeP2S12.

Tetragonal Li10GeP2S12 (LGPS) is the best solid Li ion conductor known to date. So far, the structure of the electrolyte was only determined from powder diffraction and Rietveld refinement. Here, we present the first single-crystal structure analysis of the tetragonal LGPS structure. The reported structure is largely verified. However, an additional Li position is clearly identified which might...

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Lithium Superionic Conductor Li9.42Si1.02P2.1S9.96O2.04 with Li10GeP2S12-Type Structure in the Li2S–P2S5–SiO2 Pseudoternary System: Synthesis, Electrochemical Properties, and Structure–Composition Relationships

Citation: Hori S, Suzuki K, Hirayama M, Kato Y and Kanno R (2016) Lithium Superionic Conductor Li9.42Si1.02P2.1S9.96O2.04 with Li10GeP2S12-Type Structure in the Li2S–P2S5–SiO2 Pseudoternary System: Synthesis, Electrochemical Properties, and Structure– Composition Relationships. Front. Energy Res. 4:38. doi: 10.3389/fenrg.2016.00038 lithium superionic conductor li9.42si1.02P2.1s9.96O2.04 with li...

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ژورنال

عنوان ژورنال: Physical Chemistry Chemical Physics

سال: 2013

ISSN: 1463-9076,1463-9084

DOI: 10.1039/c3cp51985f